Lewis Basicity and Affinity Scales: Data and Measurement 电子书下载
The Lewis concept of acids and bases is discussed in every general, organic and inorganic chemistry textbook. This is usually just a descriptive treatment, as it is not possible to devise a single numerical scale suitable for all occasions. However quantitative Lewis acid-base chemistry can be developed by compiling reaction-specific basicity scales which can be used in specific branches of chemistry and biochemistry.Lewis Basicity and Affinity Scales: Data and Measurementbrings together for the first time a comprehensive range of Lewis basicity/affinity data in one volume. More than 2400 equilibrium constants of acid-base reactions, 1500 complexation enthalpies, and nearly 2000 infrared and ultraviolet shifts upon complexation are gathered together in 25 thermodynamic and spectroscopic scales of basicity and/or affinity. For each scale, the definition, the method of measurement, an exhaustive database, and a critical discussion are given. All the data have been critically examined; some have been re-measured; literature gaps have been filled by original measurements; and each scale has been made homogeneous.This collection of data will enable experimental chemists to better understand and predict the numerous chemical, physical and biological properties that depend upon Lewis basicity. Chemometricians will be able to apply their methods to the data matrices constructed from this book in order to identify the factors which influence basicity and basicity-dependent properties. In addition, measured experimental basicities and affinities are essential to computational chemists for the validation, calibration and establishment of reliable computational methods for quantifying and explaining intermolecular forces and the chemical bond.Lewis Basicity and Affinity Scales: Data and Measurement is an essential single-source desktop reference for research scientists, engineers, and students in academia, research institutes and industry, in all areas of chemistry from fundamental to applied research."The book is a noteworthy piece of work and represents a timely and vast accumulation of knowledge regarding Lewis bases that brings together accurate thermodynamic and spectroscopic data on typical reference Lewis acids. As such, it should serve as a useful and general guide to basicity." J. AM. CHEM. SOC. 2011, 133, 642
尊敬的读者:
欢迎您访问我们的网站。本站的初衷是为大家提供一个共享学习资料、交换知识的平台。每位用户都可以将文件上传至网盘并分享。
然而,随着用户上传的资料增多,我们发现部分不宜或版权问题的书籍被分享到了本站。
为此,我们已经关闭了分享入口,并进行了多次书籍审查,但仍有部分内容未能彻底审查到位。
在此,我们恳请广大读者与我们共同监督,如发现任何不宜内容,请 点击此处 进行举报,我们会第一时间处理并下架相关内容。
希望我们能共建一个文明社区!感谢您的理解与支持!
猜你喜欢
- 《人生没有后悔药: 奇袭人生的5个套路》约翰·伊佐中文珍藏版 电子书下载
- 《酒吧长谈》马里奥·巴尔加斯·略萨全译修订版 电子书下载
- 《中公版·2016党政领导干部公开选拔和竞争上岗考试:主观题600例》李永新文字版 电子书下载
- 《世界重启:大灾变后,如何快速再造人类文明》 电子书下载
- 《自由学习》[美]卡尔·罗杰斯文字版 电子书下载
- 《教育的常识:尹建莉父母学堂2021年教育日历》尹建莉文字版 电子书下载
- 《给孩子讲量子力学》李淼经典版 电子书下载
- 《明宫奇案》吴蔚珍藏版 电子书下载
- 《我的原野盛宴》张炜文字版 电子书下载
- 《史记》早该这样读时殷弘文字版 电子书下载
- 《荷尔蒙战争》[澳]科迪莉亚·法恩/万垚中文译版 电子书下载
- 《人际的魅力:如何正确处理人际关系》邓世英经典版 电子书下载